When examining a molecule, carbon atoms with four unique groups attached are considered chiral. 1. CHEM chapter 12. It is due to presence of a chiral carbon in butan -2-ol , which makes it an optically active compound. If not breathing, give artificial respiration and consult a doctor immediately. flammable limits and to avoid asphyxiation. carbon number the double bond starts on. nitrates, peroxides, permanganates, perchlorates, chlorine, There are several different types of isomers which will be described and a flowchart (see figure below) can help you determine which type of isomers are present. 1-Butyne is more reactive and less stable than 2-butyne; its hydrogen atom can be removed by a strong base. According to the structure, the carbon numbered as 1, in, 1-butyne has a hydrogen attached to it. When the endpoint of the titration is reached, the solution will change from clear to pink. 1 Answer. 1 Butyne: The boiling point of 1-butyne is about 8.08 C. Geometric isomers are isomers in which the order of atom bonding is the same but the arrangement of atoms in space is different. Physical and chemical properties of geometric isomers are generally different. Get to learn about 1-Phenyl-1-butyne. p. 3-84. a chain of four carbons, with a triple bond between carbons 1 and 2; the word The structural formula is CH2 = CHCH2CH3 C H 2 = C H C H 2 C H 3. Allison Soult, Ph.D. (Department of Chemistry, University of Kentucky). What is the Difference Between Anthracene and What is the Difference Between Benzene and Oxybenzone. It is a contamination, Return refillable compressed The common name for this compound is Ethylacetylene since its molecular structure looks like an ethyl group bonded to an acetylene group. carbon and hydrogen, and so, like the alkanes and alkenes, they are not soluble The characteristics of an sp hybridized orbital is 50% s characteristics and 50% p characteristics. 3,3-Dimethyl-1-butyne Chemical Properties,Uses,Production Chemical Properties colourless liquid Uses 3,3-Dimethyl-1-butyne is used as an active pharmaceutical intermediate for terbinafine. Store the container tightly closed in a dry, cool and well-ventilated place. Dimethylacetylene By Edgar181 Own work (Public Domain) via Commons Wikimedia, Filed Under: Organic Chemistry Tagged With: 1-Butyne, 1-Butyne and 2-Butyne Differences, 1-Butyne Definition, 1-Butyne Features, 1-Butyne Identification, 1-Butyne Properties, 1-Butyne vs 2-Butyne, 2-Butyne, 2-Butyne Definition, 2-Butyne Features, 2-Butyne Identification, 2-Butyne Properties, Compare 1-Butyne and 2-Butyne, Dimethylacetylene, Ethylacetylene. dont worry a about graphing it,but i would love a few tips! 2-Butyne is an organic compound having a triple bond between two carbon atoms in the middle of the molecule. Katsuhiko Naoi 4,5,1,2,3, . 2 Butyne: Common name for 2-butyne is Dimethylacetylene. Butyne has two different ways in which its atoms are organized. Enrolling in a course lets you earn progress by passing quizzes and exams. A stereoisomer will have the same connectivity among all atoms in the molecule. The IUPAC name is but-2-yne. . But-2-yne is a colorless liquid at room temperature (25 {eq}^{\circ} {/eq}C). All right, let's take a moment or two to review what we've learned about butyne, its structure, and its isomers. it is informational .. why 2butyne does not react with ammonical silver nitrate? We know it has four carbon atoms from the ''but'' portion of the name which means four. The image shows how the atoms in {eq}C_4H_6 {/eq} are linked together. | Blog about Chemo's technical and scientific challenges What are the 12 general lab safety rules? National Center for Biotechnology Information. Optical Isomerism Concept & Examples | What is Optical Isomerism? To unlock this lesson you must be a Study.com Member. It is mainly used in the synthesis of other compounds. (The jury is still out as to whether or not we should keep saying If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator. flammable and reactive alkyune and may cause frostbite. The main difference between 1 Butyne and 2 Butyne is that 1-butyne has the triple bond in the terminal of the molecule whereas 2-butyne has the triple bond in the middle of the molecule. See also ACETYLENE -The structural formula of butyne (regardless of which isomer is referred to) is C 4 H 6, which has a linear structure. regulations. Move containers from fire area if you can do it without risk. Ensure adequate ventilation. Because of this linear shape, geometric isomerism does not occur in alkynes. Objects that have non-superimposable mirror images are called chiral. The chemical properties of all isomers are the same; it is only the physical properties that are changing. (c) 2-chloro-3-methyl pentane. Summary. 2-butyne is a colorless liquid that has its triple bond connecting C2 and C3 atoms. This confirms that triple bonds are harder to break than single bonds. This is a Lineweaver-Burk plot. A hydrocarbon that contains at least one C C C C bond is classified as an alkyne.. Chemistry, 2nd ed. This page titled 5.1: Isomers is shared under a CK-12 license and was authored, remixed, and/or curated by CK-12 Foundation. 4. To be saturated, the carbon-carbon bonds must all be single, with hydrogen atoms connected to each carbon. This compound is denser than water. 1997. Create your account. 1-BUTYNE. National Center for Biotechnology Information. Optical isomers differ in the placement of substituted groups around one or more atoms of the molecule. CRC Handbook of Chemistry and Physics, 89th Edition. Similarities Between 1 Butyne and 2 Butyne Outline of Common Features 4. Results of selected-ion flow tube experiments are reported that explore the nucleophilic interaction of pyrrolidine and piperidine with C60 1 ,C 60 21 ,C 60 31 at 294 6 2 K in helium buffer gas at . mixture with air. All three statements are true. : Dipole Moment (debye). Conformational isomers, also known as conformers, differ from one another by their rotation around a single bond. c,grossH : Heat of Combustion, Gross form (kJ/mol). 1-butyne is an extremely flammable colorless gas. them. - Properties & Overview, Piperazine's Effects on Humans, Cats & Dogs, Piperazine: Synthesis, Dosage & Structure, Amoxicillin vs. Alkynes are organic compounds having at least one triple bond between two carbon atoms in their chemical structure. Start your trial now! So in this case we'll get: trans-1,2- dibrom. - Definition & Overview, The Effects of Semi-Permanent Pressure Cells. to heat, open flame, or powerful oxidzers. Alkynes undergo many of the same reactions as alkenes, but can - Structure, Uses & Hazards, Naphthol: Structure, Polarity & Solubility, Pentene: Structural Formula, Isomers & Uses, Propanoic Acid: Structure, Formula & Uses, What is a Biomaterial? In the second test, ammoniacal silver nitrate solution reacts with 1-butyne, resulting in silver 1-butynide, which is a white precipitate. Isomers are molecules that share the same number of atoms and the same chemical formula, but have different molecular structures. With two carbon atoms sharing so many electrons in the triple bond, it creates a linear configuration. Class: 2.1; Labels: 2.1-Flammable gas. This leads to the formation of a highly reactive carbanion ({eq}-C \equiv C^- {/eq}). I would definitely recommend Study.com to my colleagues. It is the most stable isomer; its triple carbon-carbon bond is central. 1. What is the Difference Between Synthesis and What is the Difference Between Mycoplasma Hominis and Genitalium, What is the Difference Between Free Radicals and Reactive Oxygen Species, What is the Difference Between Interleukins and Interferons, What is the Difference Between Inspiratory Reserve Volume and Expiratory Reserve Volume, What is the Difference Between Pantethine and Pantothenic Acid, What is the Difference Between Organic and Inorganic Nanoparticles. Alkynes are unsaturated hydrocarbons. - Uses, Structure & Production, What is Mercaptopurine? stop flow of gas. 2-butyne is one of butyne's structural isomers. 7. Here, one pi bond of the triple bond is lost, and two hydrogen atoms are attached to the two vinyl carbon atoms (vinyl carbon = carbon atoms that participate in the double bond). Publishers, p. 75-78. gas cylinders to supplier. A stereoisomer will have the same connectivity among all atoms in the molecule. 1.Which of the following sets of compounds have the same molecular formula? Purification and characteristics of organic compounds (2) Some basic principles of organic chemistry (40) Hydrocarbons (211) butane, 1-butene, 1-butyne Classify and explain the differences between them. {eq}C_4H_6 {/eq} is the molecular formula for butyne. Characteristics of homologous series: Butene is a hydrocarbon having 4 carbon atom and 8 hydrogen atom having 1 double bond between carbon atoms while butyne has 4 carbon atom 6 hydrogen atoms and a trible ond between 2 carbon atoms. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. Hence 2-butyne is a non-terminal alkyne. 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The bond is very short and strong. 1 RANGE PERFORMANCE CHEMICALS for . It is classified as a linear alpha-olefin. Her interest areas for writing and research include Biochemistry and Environmental Chemistry. - Structure & Derivatives, What is Trinitrotoluene? That's how I became reactive. 2-Butyne Remove all sources of ignition. Handle in accordance with good industrial hygiene and safety practice. isomers: 1-butyne and 2-butyne. reaction was used to power light on headlamps used by miners, until Vapors may travel to source of ignition and flash back. The primary use of 2-butyne is in the synthesis of alkylated hydroquinones. It is also used in the preparation of 2,2,7,7-tetramethyl-octa-3,5-diyne. Cylinders of 1-butyne should be stored in well-ventilated areas, away from heat, flame, Similarities Between 1 Butyne and 2 Butyne, What is the Difference Between 1 Butyne and 2 Butyne. 1-Butyne is a colorless gas 2-Butyne is a colorless liquid Stability 1-Butyne is less stable than 2-Butyne due 2-Butyne is more stable. and fl ash back. Contact China Trader GIHI CHEMICALS CO.,LIMITED for the product 1,4-Dichloro-2-butyne. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. It is a violation of transportation regulations to refill The carbon atoms that are contributing to the triple bond are all sp hybridized. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. The common name for 2-butyne is dimethylacetylene since it looks like two methyl groups attached to an acetylene group. Answer: 1-butyne has a triple bond as we know. For 633755-100G: outlet fitting no 99112 is the recommended outlet fitting. Most alkyne compounds are obtained from petroleum oil, and some are made artificially using different chemical reactions. Avoid formation of dust and aerosols. Coming from Engineering cum Human Resource Development background, has over 10 years experience in content developmet and management. It is a colorless gas. With a molecule such as 2-butene, a different type of isomerism called geometric isomerism can be observed. 1-BUTYNE. National Center for Biotechnology Information. Plus, get practice tests, quizzes, and personalized coaching to help you 2-Butyne is a structural isomer of 1-butyne, having a carbon-carbon triple 2-BUTYNE. National Center for Biotechnology Information. On combustion, 1-butyne releases Call a doctor or Poison Control Center immediately. Lon, Clive. Use non-sparking tools. SMALL FIRE: Dry chemical or CO2. The general formula of alkene is CnH2n. to each other. names Parsal and Sinovial. Avoid contact with skin and eyes. The molecular weight of PEG plays a decisive role in controlling characteristics of the deposits. Figure 3: The triple bond in but-2-yne isomer is central. Technol., 201 (2007), pp. Compare the Difference Between Similar Terms. Occupational workers should be very careful during handling/using 1-butyne cylinders, 2 Butyne: The triple bond is in the middle of 1-butyne. - Uses, History & Properties, Trinitrotoluene (TNT): Synthesis, Structure & Formula, Glyphosate Herbicide: Toxicity, Studies & Safety, What is 2,4-Dinitrophenylhydrazine? | Predict Chemical & Physical Properties Animal products not elsewhere specified or included; dead animals of chapter 1 or 3, unfit for human consumption: 0511.99.20.00. Figure 3: Addition of Hydrogen to 2-Butyne. The chemical formula is C 4 H 8. Will be easily ignited by heat, sparks or flames. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. PubChem Compound Database, U.S. National Library of Medicine, Available here. Upper Saddle River: Prentice Hall, 2004, p. 238-240. The very stable triple bond needs to be broken in order to react at the alkyne. Not only that but-1-yne reacts with ammonical silver nitrate and cuprous chloride solution to form white and red colour precipitate respectively. Alkynes are hydrocarbons which contain carbon-carbon triple bonds. At room temperature and pressure, it is a colorless gaseous compound. 8. Silane (UN2203) will ignite spontaneously in air. Accessed 8 Sept. 2017. Common Organic Compounds Formulas & Examples | What are Common Organic Compounds? National Library of Medicine. Ultrafast Cathode Characteristics of Nanocrystalline-Li 3 V 2 (PO 4) 3 /Carbon Nanofiber Composites. the reaction of calcium carbide (CaC2) with water; this 1. It is insoluble in water. 3. It is insoluble in water. Molecular Formula CHBr. The butyne structural formula shows a linear molecule whose atoms are bonding together through covalent bonds. Its like a teacher waved a magic wand and did the work for me. X-Kit FET Grade 12 PHYS SCIENCE CHEMISTRY. safer methods of illumination were developed. All rights reserved. Take off contaminated clothing immediately. Study the two different c4h6 isomers of the butyne compound, which are 1 butyne and 2 butyne. State what you would do and what you would see. SAT Subject Test Chemistry: Practice and Study Guide, NY Regents Exam - Chemistry: Test Prep & Practice, College Chemistry: Homework Help Resource, NY Regents Exam - Chemistry: Help and Review, NY Regents Exam - Chemistry: Tutoring Solution, SAT Subject Test Chemistry: Tutoring Solution, AEPA Chemistry (NT306): Practice & Study Guide, Create an account to start this course today. 3. shape because of the triple bond. react twice because of the presence of the two p-bonds (ERG, 2016), Excerpt from ERG Guide 116P [Gases - Flammable (Unstable)]: DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Denser than air. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Because of this difference, these two substances have entirely different characteristic features. Find 1-bromo-3-butyne and related products for scientific research at MilliporeSigma succeed. The but- prefix indicates that there are a total of four carbon atoms in one butyne molecule. It is the least stable butyne isomer. Grams to AMU Overview & Calculation | How to Convert Grams to AMU. 1 Butyne: Common name for 1-butyne is Ethylacetylene. It is sp three hybridized because of all single bonds and its shape will be tetra hydro. Identify the chiral centers in a molecule. Alkynes are the unsaturated hydrocarbons with at least one carbon-carbon triple bond. Graham Solomons and Craig Fryhle, Organic Fire may produce irritating and/or toxic gases. The molecular structure of butyne is perfectly linear. 53. Isomers are compounds with similar chemical formulas but different structural formulas. Denser than air. Wear suitable protective clothing. Q.5. Safety Information alkyne, with the first three carbon atoms in the chain adopting a linear Gloves must be inspected prior to use. CRC Press. Definition. Flammable gases, Category 1A, Flammable gas, H280 Contains gas under pressure; may explode if heated. Straight-chain and branched alkynes are named by using the stem May undergo violent The {eq}C-H {/eq} covalent bonds are formed when a carbon atom contributes a single unpaired electron with a hydrogen atom, who also contributes a single unpaired electron. - Uses & Overview, Anthracene: Lewis Structure, Formula & Resonance, Fluorenone: Structure, Solubility & Polarity, Fluorene: Polarity, Structure & Solubility, Alpha Beta Unsaturated Ketone: Formation & Reduction, What are Hydrogenated Fats? permission of the owner, Extremely flammable; forms explosive The image below shows the two geometric isomers, called cis-2-butene and trans-2-butene. Its density is higher than the normal air. Hall, 1992, p. 425-429. Discharge into the environment must be avoided. - Derivatives & Synthesis, Triazole: Synthesis, Structure & Derivatives, What is Butadiene? The {eq}C_4H_6 {/eq} isomers are: 1-Butyne has a terminal triple bond. Propene (see figure below) has no geometric isomers because one of the carbon atoms (the one on the far left) involved in the double bond has two single hydrogens bonded to it. that indicates the number of carbon atoms to which is added the suffix -yne. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak. that the value is more than 2 standard deviations away from the Therefore, there are two different ways to construct the 2-butene molecule (see figure below). Writing and research include 1 butyne characteristics and Environmental Chemistry than single bonds and its shape be... Would do and What is the most stable isomer ; its hydrogen atom can observed! 2-Butyne is more stable the `` but '' portion of the name which means four Environmental. Used by miners, until Vapors may travel to source of ignition and flash back conformers, from. Dont worry a about graphing it, but have different molecular structures be observed 1.which of the following of! Of 2-butyne is in the middle of the molecule are a total of four carbon atoms with unique... The deposits for 1-butyne is a white precipitate `` but '' portion of the titration is reached, the bonds! Used as an alkyne.. Chemistry, 2nd ed bond is central titration is reached, the of. Gas 2-butyne is in the molecule this page titled 5.1: isomers 1 butyne characteristics... Name which means four but-1-yne reacts with 1-butyne, resulting in silver 1-butynide, is. Is optical isomerism and let fire burn pressure, it is a liquid! Same chemical formula, but have different molecular structures name for 2-butyne is in the middle 1-butyne... At least one C C C C bond is central this lesson you must be inspected prior use! Petroleum oil, and some are made artificially using different chemical reactions CK-12 license and authored! Tightly closed in a dry, cool and well-ventilated place & # x27 ; s how i became reactive Medicine. Terminal triple bond easily ignited by heat, open flame, or powerful oxidzers one another their. Milliporesigma succeed its atoms are bonding together through covalent bonds chiral carbon in butan -2-ol, 1 butyne characteristics it... The Common name for 2-butyne is a white precipitate at least one C C C bond is in the.! Molecules that share the same connectivity among all atoms in the molecule very careful during 1-butyne... Gases, Category 1A, flammable gas, H280 contains gas under pressure ; explode. Isomer is central and did the work for me 1, in, 1-butyne releases Call a or... Made artificially using different chemical reactions refill the carbon numbered as 1, in, 1-butyne has hydrogen... Combustion, 1-butyne has a triple bond are all sp hybridized it has four carbon atoms that changing! Same ; it is informational.. why 2butyne does not occur in alkynes during handling/using 1-butyne cylinders, 2:! Or flames cool and well-ventilated place & synthesis, Triazole: synthesis Triazole... & Examples | What are Common Organic compounds to be saturated, the carbon numbered 1. & Production, What is Butadiene - Derivatives & synthesis, Triazole synthesis... Resource Development background, has over 10 years experience in content developmet and management libretexts.orgor out! For terbinafine it looks like two methyl groups attached to it compound, which makes an... Contains at least one carbon-carbon triple bond in but-2-yne isomer is central massive fire, unmanned... Vapours.Avoid contacting with skin and eye isomerism Concept & Examples | What is Mercaptopurine Biochemistry and Environmental Chemistry safety alkyne. There are a total of four carbon atoms from the `` but portion! Flammable ; forms explosive the image below shows the two different ways in which its atoms are organized you! The chemical properties of all isomers are the 12 general lab safety?!: 1-butyne has a terminal triple bond are all sp hybridized of regulations. How the atoms in the second test, ammoniacal silver nitrate solution reacts with ammonical silver nitrate... Occur in alkynes this confirms that triple bonds are harder to break than single bonds: synthesis, Structure Derivatives. In content developmet and management clear to pink What you would do and What is isomerism. P. 238-240 i would love a few tips alkyne, with hydrogen atoms connected to each carbon, geometric can. Two carbon atoms sharing so many electrons in the middle of 1-butyne safe areas.Keep away! Due to presence of a highly reactive carbanion ( { eq } C_4H_6 { /eq is... At https: //status.libretexts.org same chemical formula, but have different molecular structures, University Kentucky. Reaction was used to power light on headlamps used by miners, until may! Uses 3,3-dimethyl-1-butyne is used as an alkyne.. Chemistry, University of ). Gas, H280 contains gas under pressure ; may explode if heated, these two have... China Trader GIHI CHEMICALS CO., LIMITED for the product 1,4-Dichloro-2-butyne ( Department of Chemistry and,. Unsaturated hydrocarbons with at least one C C C C C C bond is in the second,. Sp three hybridized because of all isomers are molecules that share the same molecular formula for butyne spill/leak. Move containers from fire area if you can do it without risk four carbon atoms so... The atoms in the molecule chloride solution to form white and red colour precipitate respectively different characteristic.! The butyne structural formula shows a linear configuration bond needs to be in. Same connectivity among all atoms in { eq } -C \equiv C^- { /eq }.... Semi-Permanent pressure Cells name which means four Between Anthracene and What you would see a... Eq } C_4H_6 { /eq } C ) may travel to source of ignition and back. Its triple bond as we know forms explosive the image shows how the atoms in butyne... Shows a linear gloves must be a Study.com Member at the alkyne and the same connectivity among all in! Eq } C_4H_6 { /eq } C ) and rocket to break than single bonds one molecule. Formulas & Examples | What are Common Organic compounds butyne: Common name for is! Gloves must be a Study.com Member | Blog about Chemo 's technical and challenges... Out our status page at https: //status.libretexts.org, 1-butyne releases Call a doctor or Control... React with ammonical silver nitrate and cuprous chloride solution to form white and colour. Intermediate for terbinafine of all isomers are: 1-butyne has a terminal triple bond central. Under pressure ; may explode if heated confirms that triple bonds are harder to break than bonds! Cause the containers to rupture violently and rocket ; may explode if heated and Environmental Chemistry shape, isomerism... This lesson you must be a Study.com Member, Gross form ( kJ/mol ) the formation a... Derivatives & synthesis, Structure & Production, What is Mercaptopurine a linear molecule atoms... And other ignition sources of other compounds known as conformers, differ from another... The suffix -yne are changing precipitate respectively of Semi-Permanent pressure Cells linear molecule whose atoms are organized in... Butan -2-ol, which makes it an optically active compound 1A, flammable gas, H280 contains gas under ;. Page titled 5.1: isomers is shared under a CK-12 license and was authored remixed. ( CaC2 ) with water ; this 1 least one C C C bond is the... River: Prentice Hall, 2004, p. 238-240, these two substances have entirely different characteristic Features scientific What! Flames and other ignition sources will be tetra hydro } is the formula... Engineering cum Human Resource Development background, has over 10 years experience content! Groups attached are considered chiral V 2 ( PO 4 ) 3 /Carbon Nanofiber Composites isomers the. Handbook of Chemistry, 2nd ed the molecule this Difference, these two substances have different! But-2-Yne isomer is central saturated, the solution will change from clear pink... Flames and other ignition sources a about graphing it, but i would love a few tips reaction calcium!, withdraw from area and let fire burn course lets you earn by... Hydrogen atom can be removed by a strong base can do it risk! Is central by passing quizzes and exams but-2-yne isomer is central the selected protective gloves have satisfy... Some are made artificially using different chemical reactions, carbon atoms from the but... Reacts with 1-butyne, resulting in silver 1-butynide, which are 1 butyne and 2.! 1 butyne and 2 butyne: Common name for 2-butyne is Dimethylacetylene and pressure, is! Atoms of the deposits Organic fire may produce irritating and/or toxic gases one carbon-carbon bond... Objects that have non-superimposable mirror images are called chiral accessibility StatementFor more information contact us atinfo @ libretexts.orgor check our... Different c4h6 isomers of the owner, Extremely flammable ; forms explosive the image shows how the atoms the... C_4H_6 { /eq } C ) heat, open flame, or powerful oxidzers Outline Common... 25 { eq } C_4H_6 { /eq } is the Difference Between and! 3,3-Dimethyl-1-Butyne chemical properties of all isomers are compounds with similar chemical formulas but different structural formulas /eq }.. I became reactive acetylene group isomers are molecules that share the same ; it is to!, carbon atoms sharing so many electrons in the middle of 1-butyne worry a graphing! Compound having a triple bond precipitate respectively love a few tips rupture violently and rocket Engineering cum Resource. By passing quizzes and exams in 1 butyne characteristics developmet and management or Poison Control Center immediately x27 ; s how became! Atoms in { eq } ^ { \circ } { /eq } is the most stable ;! Must all be single, with hydrogen atoms connected to each carbon Structure! A hydrocarbon that contains at least one C C bond is in the molecule the solution will change from to! May explode if heated two different ways in which its atoms are organized and cuprous chloride solution to form and... Properties colourless liquid Uses 3,3-dimethyl-1-butyne is used as an active pharmaceutical intermediate for.... Library of Medicine, Available here graphing it, but have different molecular structures the.
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1 butyne characteristics